Brigadier General Alfred F. Abramson III is the Program Executive Officer for PEO Ammunition.
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Mr. Chris Grassano is the [Acting] Deputy Program Executive Officer for PEO Ammunition.

Bob Kowalski is the [Acting] Chief of Staff for PEO Ammunition.

Paul Manz is the Chief Scientist for PEO Ammunition and oversees the PEO's Assured Precision Weapons and Munitions efforts.

The PEO Ammunition Human Resources is responsible for integrating the human resources management process for the PEO community, serving as the liaison and principal point of contact between PEO Ammo and servicing CPACS, Legal, EEO, etc..., maintaining the Military Acquisition Position List (MAPL) and all matters pertaining to the Army Acquisition Workforce, providing a full range of human relation advisory services for Management, Supervisors and employees, and managing the Acquisition Demo project for the PEO/DPEO and subordinate PM's.

The Director of Security and International Programs is responsible maintaining the security integrity of PEO Ammunition programs and operations. This office manages security disciplines in information, personnel, physical, industrial, communication, operations, program protection, foreign disclosure, and international technology transfer.

The Program Support Office serves as liaison between the Project Managers Offices and the Program Executive Office for Ammunition. The Program Support Office is responsible for developing PEO Ammo strategic planning on insensitive munitions, milestone decision packages and engineer support of production policy.

The G4 Office is responsible for establishing and overseeing the logistics policies of PEO Ammunition. The objective is to assure efficient and effective lifecycle logistics policies and procedures are created, implemented and executed. The office interprets DA & DoD policies with respect to Class V lifecycle logistics processes and procedures to assess their impact and assure they represent the best interests of the Warfighter, Class V community and taxpayer. The ultimate objective is assuring timely, accurate, efficient delivery of ammo in the proper condition and quantity to support and sustain the Warfighter.

The Chief Information Officer (CIO) is responsible for the design, development and maintenance of the PEO Ammunition Enterprise Portal, providing support and guidance on information technology and information assurance projects throughout the PEO community, serving as the liaison between the PEO and CIO/G6/NETCOM/DA organizations, establishing overarching policies, directives and procedures within the PEO, providing end-user support for all PEO/PM applications and tools, and representing the PEO on the Joint PEO/AMC CIO Council.

The PEO Ammunition Business Management Office is responsible for the management and execution of financial and budget processes, contracting and acquisition strategies, and cost analysis.